Multi proxy approach to evaluate and delineate the potential of hot springs in the Kotli District (Kashmir, Pakistan)

Authors

  • M. ANEES Department of earth sciences, Quaid-i-Azam University 45320 Islamabad, Pakistan. Pakistan Space and Upper Atmosphere research Commission (SUPARCo) 75270, Pakistan
  • M.M. SHAH Department of earth sciences, Quaid-i-Azam University 45320 Islamabad, Pakistan. SE-Asia Carbonate research Laboratory (SEACARL) Universiti Teknologi PETRONASCO) 32610 Seri Iskandar, Malaysia
  • A. A. QURESHI Radiation Physics Lab, Physics Department, COMSATS Institute of information Technology Islamabad, Pakistan.
  • S. MANZOOR Radiation Physics Lab, Physics Department, COMSATS Institute of information Technology Islamabad, Pakistan.

DOI:

https://doi.org/10.1344/GeologicaActa2017.15.3.5

Keywords:

Hot springs, Radon survey, Hydro-geochemistry, Geo-thermometry, Isotope composition, Geothermal system

Abstract

Tattapani hot springs are located near the Kotli District of Azad Kashmir, Pakistan. This study evaluates these hot springs based on surface geological information, radon emission measurements, hydro-geochemical and isotopic signatures and potential source mechanisms. Field observations reveal that the hot springs are located at the crest of the Tattapani anticline along the faulted contact of Cambrian carbonates with Paleocene siliciclastics. In addition, remnants of igneous intrusions in the Cambrian carbonates are commonly observed. Spatial distribution of radon emissions (ranging between 2.1 and 29.5KBq m-3) indicates an anomalous zone located over the Cambrian-Paleocene faulted contact. Hydro-geochemical data show sodium-bicarbonate affinity of hot springs. The highest surface temperature of these springs is recorded at 60.8ºC. Average reservoir temperatures based on silica and cation geo-thermometers are 101ºC and 115ºC, respectively. Giggenbach ternary diagram (Na-K-Mg) suggests a non-equilibrium state between fluid and rock, whereas isotopic and chemical data indicate heat loss by conductive cooling and mixing with groundwater during the flow of thermal water up to the surface. Oxygen and deuterium isotopes indicate that thermal water is of meteoric origin, rain and/or snow in the north at higher altitudes providing the potential recharge. Furthermore, absence of tritium in the thermal water suggests a residence time of more than 50 years.

References

Aadil, N., Rehman, T., 2013. Stratigraphy and structure of Sarda, Manil, Changpur and Naghal areas, district Kotli, Jammu and Kashmir. Journal of the Geological Society of India, 82(6), 639-648.

Ahmad, M., Tasneem, M.A., Akram, W., Hussain, S.D., Zafar, M.S., Sajjad, M.I., 2000. Isotopic investigations of Tatta Pani and Tato thermal springs: insights to their origin, age and subsurface history. Nuclear Science Journal of Malaysia (JSNM), 18(2), 95-99.

Ahmad, M., Akram, W., Hussain, S.D., Sajjad, M.I., Zafar, M.S., 2001. Origin and subsurface history of geothermal water of Murtazabad area, Pakistan-isotopic evidence. Applied Radiation and Isotopes, 55(5), 731-736.

Ahmad, M., Akram, W., Ahmad, N., Tasneem, M.A., Rafiq, M., Latif, Z., 2002. Assessment of reservoir temperatures of thermal springs of the northern areas of Pakistan by chemical and isotope geothermometry. Geothermics, 31(5), 613-631.

Ahmad, M., Sheikh, M.R., Akram, W., Tasneem, M.A., Iqbal, N., Latif, Z., 2007. Investigation of geothermal fields in Himalayan range in Pakistan using isotope and chemical techniques. Pakistan Institute of Nuclear Science and Technology, Islamabad (Pakistan). Isotope Application Division, Report PINSTECH/RIAD-202, 32pp.

APHA (American Public Health Association), 2005. Standard Methods for the Examination of Water and Wastewater. 21st

ed. American Public Health Association, Washington DC, 1220p.

Arnórsson, S., Gunnlaugsson, E., Svavarsson, H., 1983. The chemistry of geothermal waters in Iceland. III. Chemical geothermometry in geothermal investigations. Geochimica et Cosmochimica Acta, 47(3), 567-577.

Arnórsson, S., 1985. The use of mixing models and chemical geothermometers for estimating underground temperatures in geothermal systems. Journal of Volcanology and Geothermal Research, 23(3-4), 299-335.

Arnórsson, S., 2000. Isotopic and chemical techniques in geothermal exploration, development and use. International Atomic Energy Agency, 109-111.

Ashraf, M., Chaudhry, M.N., Qureshi, K.A., 1983. Stratigraphy of Kotli area of Azad Kashmir and its correlation with standard type areas of Pakistan. Kashmir Journal of Geology, 1(1), 19-30.

Ashraf, M., Chaudhry, M.N., Malik, R.H., 1986. Bituminous/anthracitic coal of Kotli District, Azad Kashmir. Kashmir Journal of Geology, 4, 1-14.

Bakht, M.S., 2000. An Overview of Geothermal Resources of Pakistan. Kyushu-Tohoku (Japan), Proceedings of the World Geothermal Congress, 77-83.

Balcazar, M., Gonzalez, E., Ortega, M., Flores, J.H., 1993. Geothermal energy prospecting in El Salvador. Nuclear Tracks and Radiation Measurements, 22(1), 273-276.

Ball, T.K., Cameron, D.G., Colman, T.B., Roberts, P.D., 1991. Behaviour of radon in the geological environment: a review. Quarterly Journal of Engineering Geology and Hydrogeology, 24(2), 169-182.

Chatterjee, S., Sharma, S., Ansari, M.A., Deodhar, A.S., Low, U., Sinha, U.K., Dash, A., 2016. Characterization of subsurface processes and estimation of reservoir temperature in Tural and Rajwadi geothermal fields, Maharashtra, India. Geothermics, 59, 77-89.

Craig, H., 1961. Isotopic variations in meteoric waters. Science, 133(3465), 1702-1703.

Epstein, S., Mayeda, T., 1953. Variation of O18 content of waters from natural sources. Geochimica et Cosmochimica Acta, 4(5), 213-224.

Faure, G., 1991. Principles and applications of inorganic geochemistry: a comprehensive textbook for geology students. USA, Macmillan Publishing Company, 626pp.

Fleischer, R.L., 1988. Radon in the environment-opportunities and hazards. Nuclear Tracks and Radiation Measurements,

, 421-435.

Fournier, R.O., 1977. Chemical geothermometers and mixing models for geothermal systems. Geothermics, 5(1), 41-50.

Fournier, R.O., 1979. Geochemical and hydrologic considerations and the use of enthalpy-chloride diagrams in the prediction of underground conditions in hot-spring systems. Journal of Volcanology and Geothermal Research, 5(1), 1-16.

Fournier, R.O., 1981. Application of water geochemistry to geothermal exploration and reservoir engineering. In: Ryback,

L., Muffler, L.J.P. (eds.). Geothermal Systems: Principles and Case Histories. New York, Wiley, 109-143.

Fournier, R.O., 1989. Lectures on geochemical interpretation of hydrothermal waters (No. 10). United Nations University Geothermal Training Programme, Iceland, Report 10, 73pp.

Mureed, S., Majeed, A., Malik, A.H., Ahmed, M., Mughal, M.N., Khan, R., Hussain, A., 2004. Geological map of Kotli area, Parts of Kotli and Sudhnoti Districts, AJK. Geological Survey of Pakistan Map Series. Vol. 6, 23, sheet no. 43 G/14. scale 1:50,000.

Giggenbach, W.F., 1988. Geothermal solute equilibria, derivation of Na-K-Mg-Ca geoindicators. Geochimica et Cosmochimica Acta, 52(12), 2749-2765.

Giggenbach, W.F., 1992. Isotopic shifts in waters from geothermal and volcanic systems along convergent plate boundaries and their origin. Earth and planetary science letters, 113(4), 495-510.

Giggenbach, W.F., Goguel, R.T., 1988. Methods for the collection and analysis of geothermal and volcanic water and gas samples. New Zealand, Department of Scientific and Industrial Research, Report, CD 2387, 53pp.

Giggenbach, W.F., Goguel, R.L., 1989. Collection and analysis of geothermal and volcanic water and gas discharges. Petone

(New Zealand), Department of Scientific and Industrial Research (DSIR), Chemistry Division, Report No.: CD 2401, 4th Edition, 88pp.

Giggenbach, W.F., Gonfiantini, R., Jangi, B.L., Truesdell, A.H., 1983. Isotopic and chemical composition of Parbati valley geothermal discharges, north-west Himalaya, India. Geothermics, 12(2-3), 199-222.

Gingrich, J.E., 1984. Radon as a geochemical exploration tool. Journal of Geochemical Exploration, 21(1), 19-39.

Haerudin, N., Munadi, S., Suryanto, W., 2013. A Soil Gas Radon Survey to Determine Fault at Southern Part of Rajabasa Geothermal Field, Lampung Indonesia. International Journal of Engineering and Technology, 13(1), 75-81.

Hussain, S.D., Asghar, G., 1982. Programme for TI Programmable Calculator for Calculation of 3 H Concentration of Water

Samples. Islamabad (Pakistan), Institute of Nuclear Science and Technology, Isotope Application Division, Report PINSTECH/RIAD-102, 45pp.

Hussain, S.D., Ahmad, M., Gonfiantini, R., Akram, W., Sajjad, M.I., Tasneem, M.A., 1995. Isotopic and chemical studies of geothermal waters of Northern Areas of Pakistan (Report IAEA-TECDOC-788). International Atomic Energy Agency (IAEA), Vienna (Austria), 127-147.

Hussain, A., Yeats, R.S., Lisa, M., 2009. Geological setting of the 8 October 2005 Kashmir earthquake. Journal of seismology,

(3), 315-325.

Levet, S., Berger, G., Munoz, M., Toutain, J. P., 2006. A new and fast method to determine mixing and conductive cooling

of thermal waters in carbonate-evaporite environments. Geothermics, 35(3), 285-301.

López, A., Gutiérrez, L., Razo, A., Balcázar, M., 1987. Radon mapping for locating geothermal energy sources. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 255(1), 426-429.

Lund, J.W., Freeston, D.H., Boyd, T.L., 2005. Direct application of geothermal energy: 2005 worldwide review. Geothermics,

(6), 691-727.

Mogro-Campero, A., Fleischer, R.L., 1977. Subterrestrial fluid convection: a hypothesis for long-distance migration of radon

within the earth. Earth and Planetary Science Letters, 34(2), 321-325.

Morawska, L., Phillips, C.R., 1993. Dependence of the radon emanation coefficient on radium distribution and internal structure of the material. Geochimica et Cosmochimica Acta, 57(8), 1783-1797.

Munir, M.U.H., Baig, M.S., 2006. Paleogene biostratigraphy of Tattapani, Kotli Azad Kashmir, Northwest sub-Himalayas, Pakistan. Journal of Himalayan Earth Sciences, 39, 39-48.

Neiva, A.M., Neiva, J.M., Parry, S.J., 1987. Geochemistry of the granitic rocks and their minerals from Serra da Estrela, Central Portugal. Geochimica et Cosmochimica Acta, 51(3), 439-454.

Nishimura, S., Katsura, I., 1990. Radon in soil gas: Applications in exploration and earthquake prediction. In: Durrance, E.M.

(Ed.), Geochemistry of Gaseous Elements and Compounds. The Ophrastus Publication, S.A. Athens, pp. 497–533.

Pearson, F.J., Rightmire, C.T., 1980. Sulphur and oxygen isotopes in aqueous sulphur compounds. Handbook of environmental isotope geochemistry, 1, 227-258.

Phuong, N. K., Harijoko, A., Itoi, R., Unoki, Y., 2012. Water geochemistry and soil gas survey at Ungaran geothermal field, central Java, Indonesia. Journal of Volcanology and Geothermal Research, 229, 23-33.

Reyes, A.G., Christenson, B.W., Faure, K., 2010. Sources of solutes and heat in low-enthalpy mineral waters and their relation to tectonic setting, New Zealand. Journal of Volcanology and Geothermal Research, 192(3), 117-141.

Sac, M.M., Harmansah, C., Camgoz, B., Sozbilir, H., 2011. Radon monitoring as the earthquake precursor in fault line in

Western Turkey. Ekoloji, 20(79), 93-98.

Sammel, E.A., Craig, R.W., 1981. The geothermal hydrology of Warner Valley, Oregon: a reconnaissance study. Reston, (Virginia, USA), Geological Survey (USGS), Professional Paper 1044-I, 147pp.

Shuja, T.A., 1986. Geothermal areas in Pakistan. Geothermics, 15(5), 719-723.

Thakur, V.C., Jayangondaperumal, R., Malik, M.A., 2010. Redefining Medlicott–Wadia’s main boundary fault from Jhelum to Yamuna: An active fault strand of the main boundary thrust in northwest Himalaya. Tectonophysics, 489(1), 29-42.

Todaka, N., Shuja, T.A., Jamiluddin, S., Khan, N.A., Pasha, M.A., Iqbal, M., 1988. A preliminary study for geothermal development project in Pakistan. Geological Survey of Pakistan Memoirs, 107, 4-47.

Tonani, F.B., 1980. Some remarks on the application of geochemical techniques in geothermal exploration. In: Strub,

A.S., Ungemach, P. (eds.). Advances in European Geothermal Research. The Netherlands, Springer, 428-443.

Toutain, J.P., Baubron, J.C., 1999. Gas geochemistry and seismotectonics: a review. Tectonophysics, 304(1), 1-27.

Truesdell, A.H., 1976. Summary of Section III-Geochemical techniques in exploration. Proceedings: 2nd United Nations Symposium on the Development and Use of Geothermal Resources. San Francisco, California, 20-29 May, 1975, vol. 1, 53-79.

Truesdell, A.H., Nathenson, M., Rye, R.O., 1977. The effects of subsurface boiling and dilution on the isotopic compositions

of Yellowstone thermal waters. Journal of Geophysical Research, 82(26), 3694-3704.

Wadia, D.N., 1928. The geology of Poonch state (Kashmir) and adjacent parts of the Panjab. India, Memoirs of Geological

Survey of India, 51, 257-268.

Watson, J.C., 1978. Sampling and analysis methods for geothermal fluids and gases (No. PNL-MA-572). Battelle Pacific Northwest Labs., Richland, WA (USA), 399pp.

Wells, N.A., Gingerich, P.D., 1987. Paleoenvironmental interpretation of Paleogene strata near Kotli, Azad Kashmir, Northeastern Pakistan. Kashmir Journal of Geology, 5, 23-41.

Whitehead, N.E., 1984. Geothermal prospecting by ground radon measurements. Journal of Volcanology and Geothermal esearch, 20(3), 213-229.

Zaigham, N.A., Nayyar, Z.A., Hisamuddin, N., 2009. Review of geothermal energy resources in Pakistan. Renewable and Sustainable Energy Reviews, 13(1), 223-232.

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2017-09-04

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