Synthesis of high ion exchange zeolites from coal fly ash
DOI:
https://doi.org/10.1344/105.000000309Keywords:
Coat fly ash, Zeolite synthesis, Metal exchange, Electroplating baths, Waste waters, Pilot plant.Abstract
This study focuses on the synthesis at a pilot plant scale of zeolitic material obtained from the coal fly ashes of the Teruel and Narcea power plants in Spain. After the optimisation of the synthesis parameters at laboratory scale, the Teruel and Narcea fly ashes were selected as low and high glass fly ashes. The pilot plant scale experiments were carried out in a 10 m3 reactor of Clariant SA (Barcelona, Spain). The results allowed obtaining 1.1 and 2.2 tonnes of zeolitic material with 40 and 55% of NaP1 content, in two single batch experiments of 24 and 8 hours, for Teruel and Narcea fly ashes, respectively. The cation exchange capacities (CEC) of the final product reached 2.0 and 2.7 meq g-1 for Teruel and Narcea zeolitic material, respectively, which are very close to the usual values reached by the high quality natural zeolitic products. Finally, with the aim of testing possible applications of the commercial NaP1-IQE and pilot plant NaP1-Narcea zeolitic products in water decontamination, efficiency for metal uptake from waste waters from electroplating baths was investigatedDownloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Copyright
The commercial rights of the printed and online versions of Geologica Acta are property of the UB, ICTJA, IDAEA and UAB, and Geologica Acta must be cited for any partial or full reproduction.
The opinions and conclusions stated in each article are the exclusive responsability of the authors and do not necessarily coincide with those of the above mentioned institutions UB, ICTJA, IDAEA and UAB.
Author Rights
Authors retain the copyright on their papers (accepted manuscript, uncorrected proof and published paper) and are authorized to post them on their own Web page or their institutional repositories. In all cases, the complete citation and a link to the Digital Object Identifier (DOI) of the article must be included.
The authors can use excerpts or reproduce illustrations of their papers in other works without prior permission of Geologica Acta provided the source of the paper including the complete citation is fully acknowledged.
Papers are distributed under the Attribution-Share Alike Creative Commons License. This license allows others to alter, remix or build upon a paper and the resulting work may be distributed under the same or similar license to this one.