Late Ediacaran carbonate production and REE+Y signatures tracing redox conditions in a Cadomian retroarc basin, Central Iberian Zone, Spain
DOI:
https://doi.org/10.1344/GeologicaActa2024.22.5Keywords:
Carbonate factory, Megabreccia, Ediacaran, Cadomian retroarc basin, GondwanaAbstract
The late Ediacaran carbonate production recorded in a Cadomian retroarc basin from the Iberian Peninsula provides an excellent opportunity to evaluate the tectonic and redox factors that controlled the infill of the foredeep troughs, located between uplifted orogenic wedges and exposed forebulge transects. In the Central Iberian Zone of the Iberian massif, the carbonates of the Villarta Formation follow two geographic belts, which represent short-term mosaics of uplifted and tilted fault-bounded basement highs. These recorded the nucleation of fringing reefal (rich in Cloudina and Sinotubulites microfossils embedded in thromboid textures) and shoal and back-barrier complexes, which episodically fed slope-related megabreccia lobes and channels. REE+Y datasets from the impure carbonates reflect contamination by detrital material, hydrothermal interaction and variable redox conditions, ranging from oxic to dysoxic, the latter emphasized by the deposition of kerogenous black shales in distal parts of the foredeep trough.
References
Álvaro, J.J., 2020. Calibrating δ13C and δ18O chemostratigraphic correlations across Cambrian strata of SW Europe and Morocco, West Gondwana. In: Montenari, M. (ed.). Carbon Isotope Stratigraphy. Stratigraphy & Time Scales, 5, 269-317.
Álvaro, J.J., Lorenzo, S., 2022. Cadomian orogenic collapse in the Ibor and Alcudia anticlines of the Central Iberian Zone, Spain. Geological Magazine, 159, 1251-1261.
Álvaro, J.J., Shields, G.A., Ahlberg, P., Jensen, S., Palacios, T., 2016. Ediacaran‒Cambrian phosphorites from the western margins of Gondwana and Baltica. Sedimentology, 63, 350-377.
Álvaro, J.J., Cortijo, I., Jensen, S., Lorenzo, S., Palacios, T., Pieren, A., 2019a. Updated stratigraphic framework and biota of the Ediacaran and Terreneuvian in the Alcudia-Toledo Mountains of the Central Iberian Zone, Spain. Estudios Geológicos, 75(2), e093.
Álvaro, J.J., Jensen, S., Palacios, T., 2019b. Post-conference fieldtrip, October 21‒24, 2019. Ediacaran and Terreneuvian strata surrounding the Villuercas-Ibores-Jara Geopark. Estudios Geológicos, 75(2), e121.
Álvaro, J.J., Cortijo, I., Jensen, S., Martí Mus, M., Palacios, T., 2020a. Cloudina-microbial reef resilience to substrate instability in a Cadomian retro-arc basin of the Iberian Peninsula. Precambrian Research, 336, 105479.
Álvaro, J.J., Sánchez-García, T., Puddu, C., Casas, J.M., Díez-Montes, A., Liesa, M., Oggiano, G., 2020b. Comparative geochemical study on Furongian‒earliest Ordovician (Toledanian) and Ordovician (Sardic) felsic magmatic events in south-western Europe: underplating of hot mafic magmas linked to the opening of the Rheic Ocean. Solid Earth, 11, 2377-2409.
Álvaro, J.J., Ortiz, J.E., Neto de Carvalho, C., López-Illa, I., Sánchez-Palencia, Y., Torres, T., 2024a. Biogenicity of amorphous organic matter and bacteriomorph acritarchs preserved in wrinkle structures from the Ediacaran Cíjara Formation, Spain. The Depositional Record, 10, 51-69.
Álvaro, J.J., Jensen, S., Valverde-Vaquero, P., 2024b. Multidisciplinary re-assessment of the Ediacaran‒Cambrian boundary interval in the Iberian Peninsula. Newsletters on Stratigraphy, 57, 323-357.
Álvaro, J.J., Lorenzo, S., Devaere, L., Warren, L.V., 2024c. Terreneuvian skeletonized microfossils from the Central Iberian Zone (Spain) and correlation of the Fortunian Stage throughout SW Europe. Palaeoworld, DOI: 10.106/j.palwor.2023.12.001.
Bandrés, A., Eguíluz, L., Gil Ibarguchi, J.I., Palacios, T., 2002. Geodynamic evolution of a Cadomian arc region: the northern Ossa-Morena Zone, Iberian Massif. Tectonophysics, 352, 105-120.
Bau, M., Dulski, P., 1996. Distribution of yttrium and rare-earth elements in the Penge and Kuruman Iron-Formations, Transvaal Supergroup, South Africa. Precambrian Research, 79, 35-55.
Byrne, R., Scholkovitz, E., 1996. Marine chemistry and geochemistry of the lanthanides. In: Gschneider, K.A., Eyring, L. (eds.). Handbook on the Physics and Chemistry of the Rare Earths. Amsterdam, Elsevier, 23, 497-593.
Calvet, F., Salas, R., 1988. Tipos de plataformas carbonatadas del Precámbrico terminal de la zona Centro-Ibérica. II Congreso de Geología de España, Granada, Comunicaciones, 1, 59-62.
Carrington da Costa, J., 1950. Noticia sobre uma carta geológica do Buçaco, de Nery Delgado. Direção Geral de Minas e Serviços Geológicos de Portugal, 28pp.
Casas, J.M., Murphy, J.B., Díez Montes, A., Sánchez-García, T., de Poulpiquet, J., Álvaro, J.J., Guimerà, J., 2024. Does the Ollo de Sapo magmatic event support Furongian‒Tremadocian mantle plume activity fringing NW Gondwana? International Geology Review, 66, 1956-1970.
Catuneanu, O., 2004. Retroarc foreland systems–evolution through time. Journal of African Earth Sciences, 38, 225-242.
Clavera-Gispert, R., Carmona Bardella, A., Gratacós Torrà, O., Tolosana-Delgado, R., 2012. Incorporating nutrients as a limiting factor in carbonate modelling. Palaeogeography, Palaeoclimatology, Palaeoecology, 329-330, 150-157.
Coletti, G., El Kateb, A., Basso, D., Cavallo, A., Spezzaferri, S., 2017. Nutrient influence on fossil carbonate factories: evidence from SEDEX extractions on Burdigalian limestones (Miocene, NW Italy and S France). Palaeogeography, Palaeoclimatology, Palaeoecology, 475, 80-92.
Cortijo, I., Martí Mus, M., Jensen, S., Palacios, T., 2010. A new species of Cloudina from the terminal Ediacaran of Spain. Precambrian Research, 176, 1-10.
Cortijo, I., Martí Mus, M., Jensen, S., Palacios, T., 2015. Late Ediacaran skeletal body fossil assemblage from the Navalpino anticline, central Spain. Precambrian Research, 267, 186-195.
DeCelles, P.G., 2012. Foreland basin systems revisited: variations in response to tectonic settings. In: Busby, C., Azor Pérez, A. (eds.). Tectonics of Sedimentary Basins: Recent Advances. Oxford, Blackwell, 405-426.
Díez Balda, M.A., Vegas, R., González Lodeiro, F., 1990. Part IV. Central Iberian Zone. Structures. In: Dallmeyer, R.D., Martínez García, E. (eds.). Pre–Mesozoic Geology of Iberia. Berlin, Springer-Verlag, 172-188.
Dorobek, S.L., 2007. Carbonate-platform facies in volcanic-arc settings: characteristics and controls on deposition and stratigraphic development. In: Draut, A., Clift, P.D., Scholl, S.W. (eds.). Formation and Application of the Sedimentary Record in Arc Collision Zones. Geological Society of America, 436 (Special Paper), 55-90.
García-Hidalgo, J.F., 1985. Estratigrafía y sedimentología del Alcudiense superior en los anticlinorios de Ibor y Navezuelas-Robledollano. Seminarios de Estratigrafía (Serie Monografías), 12, 1-190.651
Gutiérrez-Alonso, G., 1996. Strain partitioning in the footwall of the Somiedo Nappe: structural evolution of the Narcea Tectonic Window, NW Spain. Journal of Structural Geology, 18, 1217-1229.
Gutiérrez-Alonso, G., 1997. La estructura del Antiforme del Narcea y su relación con los Mantos occidentales de la Zona Cantábrica. Parte II: el sector oriental. Stvdia Geologica Salmanticensis, 33, 121-175.
Gutiérrez-Alonso, G., Fernández-Suárez, J., Weil, A.B., 2004. Orocline triggered lithospheric delamination. In: Sussman, A.J., Weil, A.B. (eds.). Orogenic Curvature: Integrating Paleomagnetic and Structural Analyses. Geological Society of America, 383 (Special Paper), 121-131.
Halfar, H., Godinez-Orta, L., Mutti, M., Valdez-Holguin, B., 2004. Nutrients and temperature controls on modern carbonate production: an example from the Gulf of California, Mexico. Geology, 32, 213-221.
Herrero, M.J., Martín-Pérez, A., Alonso-Zarza, A.M., Gil-Peña, I., Meléndez, A., Martín-García, R., 2011. Petrography and geochemistry of the magnesites and dolostones of the Ediacaran Ibor Group (635 to 542Ma), Western Spain: evidences of their hydrothermal origin. Sedimentary Geology, 240, 71-84.
Horton, B.K., 2022. Unconformity development in retroarc foreland basins: implications for the geodynamics of Andean-type margins. Journal of the Geological Society, 179, jgs2020-263.
Hufnagel, H., 2008. Kohlige Makroreste aus dem Oberen Proterozoikum der Ibor Antiklinale (Prov. Cáceres, Spanien). In: Arcega Conesa, C., Lahoz Gimeno, J. (eds.). La Vida en el Terciario: del impacto del meteorito al origen del hombre. Zaragoza, X Jornadas Aragonesas de Paleontología. Institución Fernando el Católico, 227-260.
Jensen, S., Palacios, T., 2016. The Ediacaran–Cambrian trace fossil record in the Central Iberian Zone, Iberian peninsula. Comunicaçoes Geológicas, 103, 83-92.
Jensen, S., Álvaro, J.J., Palacios, T., 2019. Pre-conference fieldtrip, October 17‒18, 2019: Ediacaran, Lower Palaeozoic and landscapes within the Villuercas-Ibores-Jara UNESCO Global Geopark. Estudios Geológicos, 75(2), e120.
Kaufman, A.J., Jacobsen, S.B., Knoll, A.H., 1993. The Vendian record of Sr- and C-isotopic variations in seawater: implications for tectonics and paleoclimate. Earth and Planetary Science Letters, 120, 409-430.
Linnemann, U., Pieren, A., Hofmann, M., Drost, K., Quesada, C., Axel, G., Marko, L., Gärtner, A., Zieger, J., Jens, U., 2018. A ~565Ma old glaciation in the Ediacaran of peri-Gondwanan West Africa. International Journal of Earth Sciences, 107, 885-911.
López Díaz, F., 1995. Late Precambrian series and structures in the Navalpino Variscan Anticline (Central Iberian Peninsula). Geologische Rundschau, 84, 151-163.
Lorenzo Álvarez, S., Solé, J., 1988. La discordancia intra–precámbrica y la estratigrafía del Precámbrico superior en el sector suroriental del Anticlinal de Abenójar-Tirteafuera. Granada, II Congreso Geológico de España, Comunicaciones, 1, 115-118.
Lotze, F., 1945. Zur Gliederung der Varisziden der Iberischen Meseta. Geotektonische Forschung, 16, 78-92.
Madukwe, H.Y., 2016. Granulometric analysis of sandstone facies of the Ise Formation, Southwestern Nigeria. Journal of Multidisciplinary Engineering Science and Technology, 3, 3909-3919.
McKay, J.L., Pedersen, T.F., Mucci, A., 2007. Sedimentary redox conditions in continental margin sediments (NE Pacific)-influence on the accumulation of redox-sensitive trace metals. Chemical Geology, 238, 180-196.
Medina, J., Rodríguez Alonso, M.D., Alonso Gavilán, G., 1998. Sedimentação em plataforma siliciclástica do Grupo das Beiras (CXG) na região de Caramulo-Buçaco (Portugal Central). Comunicaçaos do Instituto Geológico e Mineiro, 85, 39-71.
Meireles, C., Sequeira, A.J.D., Castro, P., Ferreira, N.I., 2013. New data on the lithostratigraphy of Beiras Group (Schist Greywacke Complex) in the region of Góis-Arganil-Pampilhosa da Serra (Central Portugal). Cuadernos do Laboratorio Xeolóxico de Laxe, 37, 105-124.
Menzies, C.D., Teagke, D.A.H., Craw, D., Cox, S.C., Boyce, A.J., Barrie, C.D., Roberts, S., 2014. Incursion of meteoric waters into the ductile regime in an active orogen. Earth and Planetary Science Letters, 399, 1-13.
Miall, A.D., 2016. The valuation of unconformities. Earth-Science Reviews, 163, 22-71.
Nothdurft, L.D., Webb, G.E., Kamber, B.S., 2004. Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones. Geochimica et Cosmochimica Acta, 68, 263-283.
Pacton, M., Gorin, G.E., Vasconcelos, C., 2011. Amorphous organic matter – Experimental data on formation and the role of microbes. Review of Palaeobotany and Palynology, 166, 253-267.
Palacios Medrano, T., 1989. Microfósiles de pared orgánica del Proterozoico superior (región central de la Península Ibérica). Memorias del Museo Paleontológico de la Universidad de Zaragoza, 3, 1-91.
Palacios, T., Vidal, G., 1992. Lower Cambrian acritarchs from northern Spain: the Precambrian–Cambrian boundary and biostratigraphic implications. Geological Magazine, 129, 421-436.
Palacios, T., Eguíluz, L., Apalategui, O., Jensen, S., López Torres, L., Carracedo, M., Gil Ibarguchi, J.I., Sarrioiandía, F., Martí Mus, M., 2010. Mapa Geológico de Extremadura a escala 1:250.000. Consejería de Industria, Energía y Medio Ambiente, Junta de Extremadura, Mérida, Memoria, 222pp.
Pattan, J.N., Pearce, N.J.G., Mislankar, P.G., 2005. Constraints in using Cerium-anomaly of bulk sediments as an indicator of paleo bottom water redox environment: a case study from the Central Indian Ocean Basin. Chemical Geology, 221, 260-278.
Peláez, J.R., García-Hidalgo, J.F., Moreno-Eiris, E., Herranz Araújo, P., 1988. El nivel con carbonatos del “Alcudiense Superior” en el área de Cabezarrubias-Hinojosas (Valle del Alcudia, Ciudad Real). Geogaceta, 4, 27-28.
Pereira, M.F., Chichorro, M., Linnemann, U., Eguiluz, L., Silva, J.B., 2006. Inherited arc signature in Ediacaran and Early Cambrian basins of the Ossa-Morena Zone (Iberian Massif, Portugal): paleogeographic link with European and North African Cadomian correlatives. Precambrian Research, 144, 297-315.
Pérez-Estáun, A., Martínez, F.J., 1978. El Precámbrico del antiforme del Narcea en el sector de Tineo-Cangas de Narcea (NW de España). Trabajos de Geología, Universidad de Oviedo, 10, 367-377.
Pieren Pidal, A.P., 2000. Las sucesiones anteordovícicas de la región oriental de la provincia de Badajoz y área contigua de Ciudad Real. PhD Thesis. Madrid, Universidad Complutense, 410pp.
Pieren Pidal, A.P., 2009. Rasgos geológicos de la comarca de Puertollano y del valle del Alcudia (Ciudad Real, España). Memorias de la Real Sociedad Española de Historia Natural (2ª serie), 6, 95-132.
Pieren Pidal, A.P., Herranz Araújo, P., García Gil, S., 1991. Evolución de los depósitos continentales del Proterozoico Superior en “La Serena”, Badajoz (Zona Centro lbérica). Cuadernos do Laboratorio Xeolóxico de Laxe, 16, 179-191.
Planavsky, N., Bekker, A., Rouxel, O.J., Kamber, B., Hofmann, A., Knudsen, A., Lyons, T.W., 2010. Rare earth element and yttrium compositions in Archean and Paleoproterozoic Fe formations revisited: new perspectives on the significance and mechanisms of deposition. Geochimica et Cosmochimica Acta, 74, 6387-6405.
Pourmand, A., Dauphas, N., Ireland, T.J., 2012. A novel extraction chromatography and MC-ICP-MS technique for rapid analysis of REE, Sc and Y: revising CI-chondrite and Post-Archean Australian Shale (PAAS) abundances. Chemical Geology, 291, 38-54.
Rodríguez Alonso, M.D., 1984. El complejo esquisto-grauváquico en el área de Las Hurdes y Sierra de Gata, provincias de Salamanca y Cáceres, España. Cuadernos de Geología Ibérica, 9, 37-80.
Rodríguez Alonso, M.D., Peinado, M., López-Plaza, M., Franco, P., Carnicero, A., Gonzalo, J.C., 2004. Neoproterozoic–Cambrian synsedimentary magmatism in the Central Iberian Zone (Spain): geology, petrology and geodynamic significance. International Journal of Earth Sciences, 93, 897-920.
Rubio-Ordóñez, A., Gutiérrez-Alonso, G., Valverde-Vaquero, P., Cuesta, A., Gallastegui, G., Gerdes, A., Cárdenes, A., 2015. Arc-related Ediacaran magmatism along the northern margin of Gondwana: geochronology and isotopic geochemistry from northern Iberia. Gondwana Research, 27, 216-227.
San José, M.A. de, 1984. Los materiales anteordovícicos del anticlinal de Navalpino. Cuadernos de Geología Ibérica, 9, 81-117.
San José, M.A. de, Rábano, I., Herranz, P., Gutiérrez Marco, J.C., 1992. El Paleozoico inferior de la zona Centro Ibérica meridional. In: Gutiérrez-Marco, J.C., Saavedra, J., Rábano, I. (eds.). Paleozoico Inferior de Ibero-América. Mérida, Extremadura University Press, 503-521.
Sarrionandia, F., Ábalos, B., Errandonea-Martin, J., Eguíluz, L., Santos-Zalduegui, J.F., García de Madinabeitia, S., Carrecedo-Sánchez, M., Gil Ibarguchi, J.I., 2020. Ediacaran–Earliest Cambrian arc tholeiite and adakite associations of the Malcocinado Formation (Ossa-Morena Zone, SW Spain): juvenile continental crust and deep crustal reworking in northern Gondwana. Lithos, 372-373, 105683.
Schröder, S., Grotzinger, J.P., 2007. Evidence for anoxia at the Ediacaran–Cambrian boundary: the record of redox-sensitive trace elements and rare earth elements in Oman. London, Journal of the Geological Society, 164, 175-187.
Sequeira, A.J.D., 2011. Microfossils of Beiras Group (Monfortinho – Salvaterra do extremo, Beira Baixa, Central Portugal). Comunicações Geologicas, 98, 55-60.
Shields, G., Stille, P., 2001. Diagenetic constraints on the use of cerium anomalies as palaeoseawater redox proxies: an isotopic and REE study of Cambrian phosphorites. Chemical Geology, 175, 29-48.
Simón, J., 2018. A transitional Ediacaran–Cambrian biota in the Abenójar anticline (Iberian Massif, Spain). Estudios Geológicos, 74(2), e084.
Talavera, C., Martínez Poyatos, D., González Lodeiro, F., 2015. SHRIMP U–Pb geochronological constraints on the timing of the intra–Alcudian (Cadomian) angular unconformity in the Central Iberian Zone (Iberian massif, Spain). International Journal of Earth Sciences, 104, 1739-1757.
Ugidos, J.M., Barba, P., Valladares, M.I., 2020. Review of the Upper Ediacaran–Lower Cambrian detrital series in Central and North Iberia: NE Africa as possible source area. In: Montenari, M. (ed.). Carbon Isotope Stratigraphy. Stratigraphy & Time scales, 5, 147-268.
Valladares, M.I., 1995. Siliciclastic-carbonate slope apron in an immature tensional margin (Upper Precambrian–Lower Cambrian), central Iberian Zone, Salamanca, Spain. Sedimentary Geology, 94, 165-186.
Valladares, M.I., Barba, P., Ugidos, J.M., Colmenero, J.R., Armenteros, I., 2000. Upper Neoproterozoic–Lower Cambrian sedimentary successions in the Central Iberian Zone (Spain): sequence stratigraphy, petrology and chemostratigraphy. Implications for other European zones. International Journal of Earth Sciences, 89, 2-20.
Valladares, M.I., Ugidos, J.M., Barba, P., Fallick, A.E., Ellam, R.M., 2006. Oxygen, carbon and strontium isotope records of Ediacaran carbonates in Central Iberia (Spain). Precambrian Research, 147, 354-365.
Vidal, G., Palacios, T., Gámez-Vintaned, J.A., Díaz Balda, M.A., Grant, S.W.F., 1994. Neoproterozoic–early Cambrian geology and palaeontology of Iberia. Geological Magazine, 131, 729-765.
Zhang, K., Shields, G.A., Zhou, Y., Strauss, H., Struck, U., 2024. The basal Cambrian carbon isotope excursion revealed in the Central Iberian Zone, Spain. Precambrian Research, 411, 107526 .
Downloads
Published
Issue
Section
License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Copyright
Geologica Acta is the property of the UB, GEO3BCN, IDAEA and UAB. Geologica Acta must be cited for any partial or full reproduction. Papers are distributed under the Attribution-Share Alike Creative Commons License. This license allows anyone to reproduce and disseminate the content of the journal and even make derivative works crediting authorship and provenance and distributing possible derivative works under the same or an equivalent license.
Author Rights
Authors retain the copyright on their papers and are authorized to post them on their own web pages or institutional repositories. The copyright was retained by the journal from the year 2003 until 2009. In all cases, the complete citation and a link to the Digital Object Identifier (DOI) of the article must be included.
The authors can use excerpts or reproduce illustrations of their papers in other works without prior permission from Geologica Acta provided the source of the paper including the complete citation is fully acknowledged.